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We report the first detection of the reactive ions CO⁺ and HOC⁺ toward ultracompact (UC) H II regions, particularly in Mon R2 and G29.96-0.02. We have observed two positions in Mon R2, namely, the peak of the UC H II region and the surrounding high-density molecular cloud. CO⁺ and HOC⁺ were detected at the UC H II region but not at the molecular cloud, as expected if both ions arise in the photodissociation region (PDR) surrounding the UC H II region. The measured column densities are on the order of 10¹¹ cm^–2 in both sources, which yields a strikingly low [HCO⁺]/[HOC⁺] abundance ratio of 460 in Mon R2. These values are similar to those found in some other well-known PDRs, like NGC 7023 and the Orion bar. We briefly discuss the chemical implications of these results.