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2012MNRAS.420..579G - Mon. Not. R. Astron. Soc., 420, 579-584 (2012/February-2)

Rotational relaxation and excitation rates of hydrogen fluoride in collision with ortho- and para-H2.

GUILLON G. and STOECKLIN T.

Abstract (from CDS):

We report de-excitation (and excitation) rate coefficients based on previous time-independent close-coupling scattering calculations for the rotational transitions of the hydrogen fluoride (HF) induced by collision with the two nuclear spin isomers ortho- and para-H2. These calculations were realized with the use of a new global four-dimensional potential energy surface recently computed by our group. We consider transitions for HF rotational levels up to jHF= 7, and for H2 levels up to {dot}jH2= 3 (ortho-H2) and {dot}jH2= 2 (para-H2). Rates are calculated for a range of temperatures up to 150 K. Our results show a strong difference of behaviour between ortho-H2 and para-H2 and validate the much stronger efficiency for the quenching of HF in collision with H2 in comparison with He.

Abstract Copyright: 2011 The Authors Monthly Notices of the Royal Astronomical Society2011 RAS

Journal keyword(s): molecular data - molecular processes - scattering - astronomical data bases: miscellaneous - ISM: abundances - dark ages, reionization, first stars

Simbad objects: 5

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