2013A&A...558A..62J

The evolution of amorphous hydrocarbon materials, a-C(:H), principally resulting from ultraviolet (UV) photon absorption-induced processing, are likely at the heart of the variations in the observed properties of dust in the interstellar medium. The consequences of the size-dependent and compositional variations in a-C(:H), from aliphatic-rich a-C:H to aromatic-rich a-C, are studied within the context of the interstellar dust extinction and emission. Newly-derived optical property data for a-C(:H) materials, combined with that for an amorphous forsterite-type silicate with iron nano-particle inclusions, a-Sil_Fe, are used to explore dust evolution in the interstellar medium. We present a new dust model that consists of a power-law distribution of small a-C grains and log-normal distributions of large a-Sil_Fe and a-C(:H) grains. The model, which is firmly anchored by laboratory-data, is shown to quite naturally explain the variations in the infrared (IR) to far-ultraviolet (FUV) extinction, the 217nm UV bump, the IR absorption and emission bands and the IR-mm dust emission. The major strengths of the new model are its inherent simplicity and built-in capacity to follow dust evolution in interstellar media. We show that mantle accretion in molecular clouds and UV photo-processing in photo-dominated regions are likely the major drivers of dust evolution.