2011A&A...532A..12L


C.D.S. - SIMBAD4 rel 1.7 - 2019.12.14CET13:41:35

2011A&A...532A..12L - Astronomy and Astrophysics, volume 532A, 12-12 (2011/8-1)

Differential adsorption of complex organic molecules isomers at interstellar ice surfaces.

LATTELAIS M., BERTIN M., MOKRANE H., ROMANZIN C., MICHAUT X., JESECK P., FILLION J.-H., CHAABOUNI H., CONGIU E., DULIEU F., BAOUCHE S., LEMAIRE J.-L., PAUZAT F., PILME J., MINOT C. and ELLINGER Y.

Abstract (from CDS):

Over 20 of the ∼150 different species detected in the interstellar and circumstellar media have also been identified in icy environments. For most of the species observed so far in the interstellar medium (ISM), the most abundant isomer of a given generic chemical formula is the most stable one (minimum energy principle - MEP) with few exceptions such as, for example, CH3COOH/HCOOCH3 and CH3CH2OH/CH3OCH3, whose formation is thought to occur on the icy mantles of interstellar grains. We investigate whether differences found in the compositions of molecular ices and the surrounding gas phase could originate from differences between the adsorption of one isomer from that of another at the ice surface. We performed a coherent and concerted theoretical/experimental study of the adsorption energies of the four molecules mentioned above, i.e. acetic acid (AA)/methyl formate (MF) and ethanol (EtOH)/dimethyl ether (DME) on the surface of water ice at low temperature. The question was first addressed theoretically at LCT using solid state periodic density functional theory (DFT) to represent the organized solid support. The experimental determination of the ice/molecule interaction energies was then carried out independently by two teams at LPMAA and LERMA/LAMAp using temperature programmed desorption (TPD) under an ultra-high vacuum (UHV) between 70 and 160K. For each pair of isomers, theory and experiments both agree that the most stable isomer (AA or EtOH) interacts more efficiently with the water ice than the higher energy isomer (MF or DME). This differential adsorption can be clearly seen in the different desorption temperatures of the isomers. It is not related to their intrinsic stability but instead to both AA and EtOH producing more and stronger hydrogen bonds with the ice surface. We show that hydrogen bonding may play an important role in the release of organic species from grains and propose that, depending on the environment, differential adsorption should not be rejected as a possible way of interpreting MEP exceptions.

Abstract Copyright:

Journal keyword(s): astrochemistry - ISM: abundances - ISM: molecules

Simbad objects: 1

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Number of rows : 1

N Identifier Otype ICRS (J2000)
RA
ICRS (J2000)
DEC
Mag U Mag B Mag V Mag R Mag I Sp type #ref
1850 - 2020
#notes
1 NAME Large Molecule Heimat MoC 17 47 20.4943 -28 22 11.656           ~ 109 0

    Equat.    Gal    SGal    Ecl

C.D.S. - SIMBAD4 rel 1.7 - 2019.12.14CET13:41:35

Available data : Basic data  •  Identifiers  •  Plot & images  •  Bibliography  •  Measurements  •  External archives  •  Notes  •  Annotations


Basic data :
NAME Large Molecule Heimat -- Molecular Cloud
Origin of the objects types :

(Ref) Object type as listed in the reference "Ref"
(acronym) Object type linked to the acronym according to the original reference
() Anterior to 2007, before we can link the objet type to a reference, or given by the CDS team in some particular cases

Other object types:
MoC (), mm (BGPS), smm (JCMTSF)
Syntax of coordinates is : "ra dec (wtype) [error ellipse] quality bibcode" :
  • ra dec : right ascension and declination (unit and frame defined according to your Output Options)
    Grey values are increasing the original precision due to the computation of frame transformations
  • (wtype) : wavelength class for the origin of the coordinates (Rad, mm, IR, Optical, UV, Xray, Gam)
  • [error ellipse] : measurement uncertainty, on (ra,dec) if the positional angle is 90 degrees, on (majaxis,minaxis) otherwise (in mas at defined epoch in the original catalogue),
    position angle (in degrees North celestial pole to East)
  • quality : flag of quality
    • E ≥ 10"
    • D : 1-10" (and some old data)
    • C : 0.1-1"
    • B : 0.01-0.1" + 2MASS, Tyc
    • A : VLBI, Hipparcos
  • bibcode : bibcode of the coordinates reference
ICRS coord. (ep=J2000) :
17 47 20.4943 -28 22 11.656 (mm) [ ] E 2010ApJS..188..123R
Syntax of coordinates is : "ra dec (wtype) [error ellipse] quality bibcode" :
  • ra dec : right ascension and declination (unit and frame defined according to your Output Options)
    Grey values are increasing the original precision due to the computation of frame transformations
  • (wtype) : wavelength class for the origin of the coordinates (Rad, mm, IR, Optical, UV, Xray, Gam)
  • [error ellipse] : measurement uncertainty, on (ra,dec) if the positional angle is 90 degrees, on (majaxis,minaxis) otherwise (in mas at defined epoch in the original catalogue),
    position angle (in degrees North celestial pole to East)
  • quality : flag of quality
    • E ≥ 10"
    • D : 1-10" (and some old data)
    • C : 0.1-1"
    • B : 0.01-0.1" + 2MASS, Tyc
    • A : VLBI, Hipparcos
  • bibcode : bibcode of the coordinates reference
FK4 coord. (ep=B1950 eq=1950) :
17 44 10.7086 -28 21 09.408 [ ]
Syntax of coordinates is : "ra dec (wtype) [error ellipse] quality bibcode" :
  • ra dec : right ascension and declination (unit and frame defined according to your Output Options)
    Grey values are increasing the original precision due to the computation of frame transformations
  • (wtype) : wavelength class for the origin of the coordinates (Rad, mm, IR, Optical, UV, Xray, Gam)
  • [error ellipse] : measurement uncertainty, on (ra,dec) if the positional angle is 90 degrees, on (majaxis,minaxis) otherwise (in mas at defined epoch in the original catalogue),
    position angle (in degrees North celestial pole to East)
  • quality : flag of quality
    • E ≥ 10"
    • D : 1-10" (and some old data)
    • C : 0.1-1"
    • B : 0.01-0.1" + 2MASS, Tyc
    • A : VLBI, Hipparcos
  • bibcode : bibcode of the coordinates reference
Gal coord. (ep=J2000) :
000.6800692 -00.0285579 [ ]
Syntax of angular size is : "maj-axis min-axis angle (wtype) quality bibcode"
  • maj-axis : major axis size (arc minutes)
  • min-axis : minor axis size (arc minutes)
  • angle : orientation angle (in degrees)
  • (incl) : inclination (in units of 15° from 0 to 7)
  • (wtype) : wavelength class for the origin of the angular size (Rad, mm, IR, Opt, UV, Xray, Gam)
  • quality : flag of quality of the angular size values ( A=best quality -> E=worst quality, {� } =unknown quality)
  • bibcode : bibcode of the angular size reference
Angular size (arcmin):
0.74 0.44 71 (mm) D 2010ApJS..188..123R
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Identifiers (6) :
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NAME Sgr B2(N)-LMH JCMTSF J174720.1-282214 NAME Sgr B2 (LMH)
BGPS G000.680-00.029 NAME Large Molecule Heimat NAME Sgr B2 (N-LMH)

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References (109 between 1850 and 2020) (Total 109)
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2019.12.14-13:41:35

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