2012A&A...540A.110S

As revealed by high-resolution spectral investigations in the wavelength range between 300 and 400 nm, the interstellar extinction curve does not display any of the sharp electronic absorption bands that are characteristic for large polyatomic molecules, such as polycyclic aromatic hydrocarbons (PAHs), which belong to the most abundant interstellar molecules. We aim to verify whether the absorption curves of mixtures of medium-sized PAHs produced in the laboratory can explain the astronomical observations. The PAH mixtures were synthesized by infrared laser pyrolysis and subsequent chemical extraction and size separation. The matrix isolation technique was used to study the absorption spectra of isolated molecules at low temperature. Our experimental results demonstrate that the UV-visible absorption curves of PAH mixtures can be very smooth, displaying no sharp bands, if the molecular diversity is sufficiently high. In view of the absence of sharp electronic features on the interstellar extinction curve for 300<λ<400nm, we conclude from our experimental findings that the interstellar PAH population must be very diverse. The low fractional abundances of individual species prevent their detection on the basis of spectral fingerprints in the UV.