C.D.S. - SIMBAD4 rel 1.7 - 2021.04.12CEST02:55:47

2015A&A...584A.124F - Astronomy and Astrophysics, volume 584A, 124-124 (2015/12-1)

Water deuteration and ortho-to-para nuclear spin ratio of H2 in molecular clouds formed via the accumulation of HI gas.


Abstract (from CDS):

We investigate the water deuteration ratio and ortho-to-para nuclear spin ratio of H2 (OPR(H2)) during the formation and early evolution of a molecular cloud, following the scenario that accretion flows sweep and accumulate HI gas to form molecular clouds. We follow the physical evolution of post-shock materials using a one-dimensional shock model, combined with post-processing gas-ice chemistry simulations. This approach allows us to study the evolution of the OPR(H2) and water deuteration ratio without an arbitrary assumption of the initial molecular abundances, including the initial OPR(H2). When the conversion of hydrogen into H2 is almost complete the OPR(H2) is already much smaller than the statistical value of three because of the spin conversion in the gas phase. As the gas accumulates, the OPR(H2) decreases in a non-equilibrium manner. We find that water ice can be deuterium-poor at the end of its main formation stage in the cloud, compared to water vapor observed in the vicinity of low-mass protostars where water ice is sublimated. If this is the case, the enrichment of deuterium in water should mostly occur at somewhat later evolutionary stages of star formation, i.e., cold prestellar/protostellar cores. The main mechanism to suppress water ice deuteration in the cloud is the cycle of photodissociation and reformation of water ice, which efficiently removes deuterium from water ice chemistry. The removal efficiency depends on the main formation pathway of water ice. The OPR(H2) plays a minor role in water ice deuteration at the main formation stage of water ice.

Abstract Copyright:

Journal keyword(s): astrochemistry - ISM: clouds - ISM: molecules

Simbad objects: 3

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Number of rows : 3

N Identifier Otype ICRS (J2000)
ICRS (J2000)
Mag U Mag B Mag V Mag R Mag I Sp type #ref
1850 - 2021
1 TMC-1 MoC 04 41 45.9 +25 41 27           ~ 1410 0
2 LDN 183 MoC 15 54 12.2 -02 49 42           ~ 702 1
3 NAME dze Oph Cloud Cld 16 37 09 -10 34.0           ~ 106 0

    Equat.    Gal    SGal    Ecl

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