2002A&A...384..545R

We present the evidence for abundance stratification in the atmosphere of the rapidly oscillating Ap star γ Equ. Ca, Cr, Fe, Ba, Si, Na seem to be overabundant in deeper atmospheric layers, but normal to underabundant in the upper layers with a transition in the typical line forming region of -1.5<logτ₅₀₀₀←0.5. This stratification profile agrees well with diffusion theory for Ca and Cr, developed for cool magnetic stars with a weak mass loss of ≃2.5x10^–15M_☉/yr. Pr and Nd from the rare earth elements have an opposite profile. Their abundance is more than 6dex higher above logτ₅₀₀₀≃-8.0 than in the deeper atmospheric layers. We further discuss the implications of abundance stratification in the context of radial velocity amplitudes and phases observed by Kochukhov & Ryabchikova (2001A&A...374..615K) for a variety of spectral lines and elements using high spectral and time resolved, high S/N observations.