2017A&A...604A..26D

Query : 2017A&A...604A..26D

2017A&A...604A..26D - Astronomy and Astrophysics, volume 604A, 26-26 (2017/8-1)

Doubly 15N-substituted diazenylium: THz laboratory spectra and fractionation models.

DORE L., BIZZOCCHI L., WIRSTROM E.S., DEGLI ESPOSTI C., TAMASSIA F. and CHARNLEY S.B.

Abstract (from CDS):

Context. Isotopic fractionation in dense molecular cores has been suggested as a possible origin of large 14N/15N ratio variations in solar system materials. While chemical models can explain some observed variations with different fractionation patterns for molecules with -NH or -CN functional groups, they fail to reproduce the observed ratios in diazenylium (N2H+).
Aims. Observations of doubly 15N-substituted species could provide important constraints and insights for theoretical chemical models of isotopic fractionation. However, spectroscopic data are very scarce.
Methods. The rotational spectra of the fully 15N-substituted isopologues of the diazenylium ion, 15N2H+ and 15N2D+, have been investigated in the laboratory well into the THz region by using a source-modulation microwave spectrometer equipped with a negative glow discharge cell. An extended chemical reaction network has been used to estimate what ranges of 15N fractionation in doubly 15N-substituted species could be expected in the interstellar medium (ISM).
Results. For each isotopologue of the H- and D-containing pair, nine rotational transitions were accurately measured in the frequency region 88 GHz-1.2 THz. The analysis of the spectrum provided very precise rest frequencies at millimeter and sub-millimeter wavelengths, useful for the radioastronomical identification of the rotational lines of 15N2H+ and 15N2D+ in the ISM.

Abstract Copyright: © ESO, 2017

Journal keyword(s): astrochemistry - molecular data - methods: laboratory: molecular - techniques: spectroscopic - ISM: molecules - ISM: molecules

Simbad objects: 1

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Number of rows : 1
N Identifier Otype ICRS (J2000)
RA 		ICRS (J2000)
DEC 		Mag U Mag B Mag V Mag R Mag I Sp type #ref
1850 - 2024 		#notes
1 LDN 1544 DNe 05 04 16.6 +25 10 48           ~ 863 0

Query : 2017A&A...604A..26D

Basic data :
LDN 1544 -- Dark Cloud (nebula)
Origin of the objects types :

(Ref) Object type as listed in the reference "Ref"
(acronym) Object type linked to the acronym according to the original reference
() Anterior to 2007, before we can link the objet type to a reference, or given by the CDS team in some particular cases

Other object types: 		DNe (LDN)
Syntax of coordinates is : "ra dec (wtype) [error ellipse] quality bibcode" :
  • ra dec : right ascension and declination (unit and frame defined according to your Output Options)
    Grey values are increasing the original precision due to the computation of frame transformations
  • (wtype) : wavelength class for the origin of the coordinates (Rad, mm, IR, Optical, UV, Xray, Gam)
  • [error ellipse] : measurement uncertainty, on (ra,dec) if the positional angle is 90 degrees, on (majaxis,minaxis) otherwise (in mas at defined epoch in the original catalogue),
    position angle (in degrees North celestial pole to East)
  • quality : flag of quality
    • E ≥ 10"
    • D : 1-10" (and some old data)
    • C : 0.1-1"
    • B : 0.01-0.1" + 2MASS, Tyc
    • A : VLBI, Hipparcos
  • bibcode : bibcode of the coordinates reference
ICRS coord. (ep=J2000) : 		05 04 16.6 +25 10 48 (Radio) [ ] D 2004ApJS..152...81P
Syntax of coordinates is : "ra dec (wtype) [error ellipse] quality bibcode" :
  • ra dec : right ascension and declination (unit and frame defined according to your Output Options)
    Grey values are increasing the original precision due to the computation of frame transformations
  • (wtype) : wavelength class for the origin of the coordinates (Rad, mm, IR, Optical, UV, Xray, Gam)
  • [error ellipse] : measurement uncertainty, on (ra,dec) if the positional angle is 90 degrees, on (majaxis,minaxis) otherwise (in mas at defined epoch in the original catalogue),
    position angle (in degrees North celestial pole to East)
  • quality : flag of quality
    • E ≥ 10"
    • D : 1-10" (and some old data)
    • C : 0.1-1"
    • B : 0.01-0.1" + 2MASS, Tyc
    • A : VLBI, Hipparcos
  • bibcode : bibcode of the coordinates reference
FK4 coord. (ep=B1950 eq=1950) : 		05 01 12.5 +25 06 40 [ ]
Syntax of coordinates is : "ra dec (wtype) [error ellipse] quality bibcode" :
  • ra dec : right ascension and declination (unit and frame defined according to your Output Options)
    Grey values are increasing the original precision due to the computation of frame transformations
  • (wtype) : wavelength class for the origin of the coordinates (Rad, mm, IR, Optical, UV, Xray, Gam)
  • [error ellipse] : measurement uncertainty, on (ra,dec) if the positional angle is 90 degrees, on (majaxis,minaxis) otherwise (in mas at defined epoch in the original catalogue),
    position angle (in degrees North celestial pole to East)
  • quality : flag of quality
    • E ≥ 10"
    • D : 1-10" (and some old data)
    • C : 0.1-1"
    • B : 0.01-0.1" + 2MASS, Tyc
    • A : VLBI, Hipparcos
  • bibcode : bibcode of the coordinates reference
Gal coord. (ep=J2000) : 		177.9797 -09.7308 [ ]
Syntax of radial velocity (or/and redshift) is : "value [error] (wavelength) quality bibcode"
  • value : radial velocity or/and redshift (Heliocentric frame) according to your Output Options
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  • [error] : error of the corresponding value displayed before
  • (wavelength) : wavelength range of the measurement : Rad, mm, IR, Opt, UV, Xray, Gam or  '∼'(unknown)
  • quality : flag of quality ( A=best quality -> E=worst quality, ∼=unknown quality)
  • bibcode : bibcode of the value's origin
Radial velocity / Redshift / cz : 		V(km/s) 6.95 [~] / z(~) 0.000023 [~] / cz 6.95 [~]
   D 1978ApJ...221L.117H
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LDN 1544

References (863 between 1850 and 2024) (Total 863)
Simbad bibliographic survey began in 1850 for stars (at least bright stars) and in 1983 for all other objects (outside the solar system).
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