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2013A&A...549A..96H - Astronomy and Astrophysics, volume 549A, 96-96 (2013/1-1)

Millimeter and submillimeter wave spectra of 13C-glycolaldehydes.

HAYKAL I., MOTIYENKO R.A., MARGULES L. and HUET T.R.

Abstract (from CDS):

Glycolaldehyde (CH2OHCHO) is the simplest sugar and an important intermediate in the path toward forming more complex biologically relevant molecules. Astronomical surveys of interstellar molecules, such as those available with the very sensitive ALMA telescope, require preliminary laboratory investigations of the microwave and submillimeter-wave spectra of molecular species including new isotopologs - to identify these in the interstellar media. To achieve the detection of the 13C isotopologs of glycolaldehyde in the interstellar medium, their rotational spectra in the millimeter and submillimeter-wave regions were studied. The spectra of 13CH2OHCHO and CH2OH13CHO were recorded in the 150-945GHz spectral range in the laboratory using a solid-state submillimeter-wave spectrometer in Lille. The observed line frequencies were measured with an accuracy of 30kHz up to 700GHz and of 50kHz above 700GHz. We analyzed the spectra with a standard Watson Hamiltonian. About 10000 new lines were identified for each isotopolog. The spectroscopic parameters were determined for the ground- and the three lowest vibrational states up to 945 and 630GHz. Previous microwave assignments of 13CH2OHCHO were not confirmed. The provided line-lists and sets of molecular parameters meet the needs for a first astrophysical search of 13C-glycolaldehydes.

Abstract Copyright:

Journal keyword(s): ISM: molecules - submillimeter: ISM - methods: laboratory - line: identification

VizieR on-line data: <Available at CDS (J/A+A/549/A96): table3.dat table4.dat>

Simbad objects: 2

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